Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Three-Dimensionally Ordered Macroporous ZrO2:Eu3+: Photonic Band Effect and Local Environments | |
其他题名 | 论文其他题名 |
Qu X.; Song H. W.; Pan G. H.; Bai X.; Dong B. A.; Zhao H. F.; Dai Q. L.; Zhang H.; Qin R. F.; Lu S. Z. | |
2009 | |
发表期刊 | Journal of Physical Chemistry C |
ISSN | 1932-7447 |
卷号 | 113期号:15页码:5906-5911 |
摘要 | Three-dimensionally ordered macroporous (3DOM) ZrO2:Eu3+ inverse opal materials prepared by polystyrene (PS) colloidal crystal templating, using the sol-gel method, were successfully fabricated. Their crystal structure, morphology, and photoluminescence (PL) properties and the effect of the photonic stop-band on the spontaneous emission of Eu3+ ions were studied and compared with those of the nonporous sample. In the 3DOM ZrO2: Eu3+, significant suppression for the 5D(0)-F-7(1) transition peaking at 590 nm was observed, which was in good agreement with the photonic band gap calculated (similar to 586 nm). After grinding the 3D ZrO2:Eu3+ inverse opal material, the suppression of emission was restored due to the disappearance of the photonic band gap. In the 3DOM ZrO2:Eu3+, the luminescent lifetime of D-5(0)-F-7(J) depended strongly on emission wavelengths, which was mainly attributed to the appearance of different Eu3+ centers. In the 3DOM ZrO2:Eu3+, three symmetry sites for Eu3+ were identified by site-selective excitation, differing from the nonporous sample, in which only one site was identified. |
收录类别 | SCI ; EI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/26251 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Qu X.,Song H. W.,Pan G. H.,et al. Three-Dimensionally Ordered Macroporous ZrO2:Eu3+: Photonic Band Effect and Local Environments[J]. Journal of Physical Chemistry C,2009,113(15):5906-5911. |
APA | Qu X..,Song H. W..,Pan G. H..,Bai X..,Dong B. A..,...&Lu S. Z..(2009).Three-Dimensionally Ordered Macroporous ZrO2:Eu3+: Photonic Band Effect and Local Environments.Journal of Physical Chemistry C,113(15),5906-5911. |
MLA | Qu X.,et al."Three-Dimensionally Ordered Macroporous ZrO2:Eu3+: Photonic Band Effect and Local Environments".Journal of Physical Chemistry C 113.15(2009):5906-5911. |
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