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Synthesis and characterization of nanoporous NaYF4:Yb3+, Tm3+@SiO2 nanocomposites
其他题名论文其他题名
Liu L. N.; Li B.; Qin R. F.; Zhao H. F.; Ren X. G.; Su Z. M.
2010
发表期刊Solid State Sciences
ISSN1293-2558
卷号12期号:3页码:345-349
摘要Novel upconversion nanocomposites with nanoporous structure were presented in this paper. Silica-coated cubic NaYF4:Yb3+, Tm3+ nanoparticles were first prepared. After annealing, monodisperse cubic/hexagonal mixed phases NaYF4:Yb3+, Tm3+@SiO2 nanoparticles were obtained, and the NaYF4:Yb3+, Tm3+ cores became nanoporous. To the best of our knowledge, the nanoporous structure in NaYF4:Yb3+, Tm3+@SiO2 nanocomposites was observed for the first time. They demonstrate increased upconversion emission compared with unannealed dense NaYF4:Yb3+, Tm3+ nanoparticles due to the appearance of the hexagonal NaYF4:Yb3+, Tm3+. The silica shell not only makes the nanocomposites possess bio-affinity but also protects the NaYF4:Yb3+, Tm3+ cores from aggregating and growing up. Thus the upconversion, nanoporous and bio-affinity properties were combined into one single nanoparticle. The nanocomposites have been characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), small angle X-ray diffraction (SAXRD) and emission spectroscopy. These multifunctional nanocomposites are expected to find applications in biological fields, such as biolabels, drug storage and delivery. (C) 2009 Elsevier Masson SAS. All rights reserved.
收录类别SCI ; EI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/26148
专题中科院长春光机所知识产出
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Liu L. N.,Li B.,Qin R. F.,et al. Synthesis and characterization of nanoporous NaYF4:Yb3+, Tm3+@SiO2 nanocomposites[J]. Solid State Sciences,2010,12(3):345-349.
APA Liu L. N.,Li B.,Qin R. F.,Zhao H. F.,Ren X. G.,&Su Z. M..(2010).Synthesis and characterization of nanoporous NaYF4:Yb3+, Tm3+@SiO2 nanocomposites.Solid State Sciences,12(3),345-349.
MLA Liu L. N.,et al."Synthesis and characterization of nanoporous NaYF4:Yb3+, Tm3+@SiO2 nanocomposites".Solid State Sciences 12.3(2010):345-349.
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