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SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE
Alternative Title论文其他题名
Wang R. F.; Jin L. P.; Wang M. Z.; Huang S. H.; Chen X. T.
1995
Source PublicationActa Chimica Sinica
ISSN0567-7351
Volume53Issue:1Pages:39-45
AbstractThe coordination compound of europium p-methylbenzoate with 2,2 '-dipyridine was synthesized and characterized by elemental analysis and infrared spectrum. The crystal structure of the title compound, Eu-2(p-MBA)(6)(dipy)(2) (p-MBA: p-methylbenzoate, dipy: 2,2 '-dipyridine) was determined by the X ray diffraction analysis. It crystallizes in the monoclinic C2/c system with unit cell dimensions a=1.4086(6), b=1.9115(11), c=2.3077(16)nm; beta=96.60(4)degrees, V=6.1727nm(3) and Z=4. The metal atoms are octa-coordinated with the bidentates of p-methylbenzoate and 2,2 '-dipyridine. Since the title coordination compound Eu(p-MBA), dipy fluoresces very intensely under ultraviolet or visible light. Using Eu(III) ion as luminescent probe, the high-resolution laser excited excitation and luminescence spectra and time resolved spectra were recorded at 77K. The emission spectra indicate that two Eu(III) ion sites are present in the compound .
Indexed BySCI
Language中文
WOS IDWOS:A1995QH85200007
Citation statistics
Cited Times:54[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.ciomp.ac.cn/handle/181722/25968
Collection中科院长春光机所知识产出
Recommended Citation
GB/T 7714
Wang R. F.,Jin L. P.,Wang M. Z.,et al. SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE[J]. Acta Chimica Sinica,1995,53(1):39-45.
APA Wang R. F.,Jin L. P.,Wang M. Z.,Huang S. H.,&Chen X. T..(1995).SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE.Acta Chimica Sinica,53(1),39-45.
MLA Wang R. F.,et al."SYNTHESIS, CRYSTAL-STRUCTURE AND LUMINESCENCE OF COORDINATION COMPOUND OF EUROPIUM P-METHYLBENZOATE WITH 2,2'-DIPYRIDINE".Acta Chimica Sinica 53.1(1995):39-45.
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