Crystal structure and luminescence spectra of novel coordination layer of { Eu(m-BDC) (NO3) (Phen) (H2O) (2) center dot 2CH(3) CH2OH}(n)

	Crystal structure and luminescence spectra of novel coordination layer of { Eu(m-BDC) (NO3) (Phen) (H2O) (2) center dot 2CH(3) CH2OH}(n)
其他题名	论文其他题名
	Wang M. Z.; Xia J. B.; Cai G. L.; Lu S. Z.
	2005
发表期刊	Journal of Rare Earths
ISSN	1002-0721
卷号	23 期号:2 页码:138-142
摘要	The crystal structure of a novel Eu3+ coordination polymer, {[Eu (m-BDC) (NO3) (Phen) (H2O)](2) (.) 2CH(3)CH(2)OH}(n) (m-BDC = 1, 3-benzenedicarboxylate, Phen = 1, 10-phenanthroline), was obtained and its high-resolution luminescence spectra at 77K were measured. The mu(2)-carboxylate of m-BDC constructs the binuclear building block in which each EU ion is coordinated by four oxygen atoms of m-BDC anions, one oxygen atom from water molecule, two oxygen atoms of nitrate and two nitrogen atoms of Phen, respectively. The mu(2)-carboxylate of m-BDC conjugates the binuclear units one-dimensional chain or a ribbon, while the hydrogen bonds between ribbons assemble the structure two-dimensional layer with a thickness equaling to the width of the ribbon. The luminescence spectra reveal that the two Eu3+ ion sites in the binuclear building blocks have slight environmental difference. The C, local symmetry of Eu3+ ion is concluded from both crystal structure measurement and luminescence spectra.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/25772
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Wang M. Z.,Xia J. B.,Cai G. L.,et al. Crystal structure and luminescence spectra of novel coordination layer of { Eu(m-BDC) (NO3) (Phen) (H2O) (2) center dot 2CH(3) CH2OH}(n)[J]. Journal of Rare Earths,2005,23(2):138-142.
APA	Wang M. Z.,Xia J. B.,Cai G. L.,&Lu S. Z..(2005).Crystal structure and luminescence spectra of novel coordination layer of { Eu(m-BDC) (NO3) (Phen) (H2O) (2) center dot 2CH(3) CH2OH}(n).Journal of Rare Earths,23(2),138-142.
MLA	Wang M. Z.,et al."Crystal structure and luminescence spectra of novel coordination layer of { Eu(m-BDC) (NO3) (Phen) (H2O) (2) center dot 2CH(3) CH2OH}(n)".Journal of Rare Earths 23.2(2005):138-142.

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