Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Crystal structure and luminescence of europium 4-methoxybenzoate complex with 2,2 '-bipyridine Eu(p-MOBA)(3)bipy center dot 1/2C(2)H(5)OH | |
其他题名 | 论文其他题名 |
Jin L. P.; Wang R.![]() | |
1999 | |
发表期刊 | Polyhedron
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ISSN | 0277-5387 |
卷号 | 18期号:3—4页码:487-491 |
摘要 | Europium 4-methoxybenzoate complex with 2,2'-bipyridine, [Eu(p-MOBA)(3)bipyl] . 1/2C(2)H(5)OH (where p-MOBA = 4-methoxybenzoate and bipy = 2,2'-bipyridine), was obtained in the ethanol solution and the crystal structure was determined by X-ray diffraction. The crystal consists of binuclear molecules of the title compound. In the complex each Eu3+ ion is nine-coordinate to one bipyridine molecule, one bidentate carboxylate group and four bridging carboxylate groups in which the carboxylate groups are bonded to the europium ion in three modes: the chelating bidentate, the bridging bidentate and the bridging tridentate. Excitation and luminescence data observed at 77 K show that the Eu(3+)ion site in the complex has low symmetry and when excited a slight change of chemical environments of the Eu3+ ion is observed. (C) 1998 Elsevier Science Ltd. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25321 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Jin L. P.,Wang R.,Li L. S.,et al. Crystal structure and luminescence of europium 4-methoxybenzoate complex with 2,2 '-bipyridine Eu(p-MOBA)(3)bipy center dot 1/2C(2)H(5)OH[J]. Polyhedron,1999,18(3—4):487-491. |
APA | Jin L. P.,Wang R.,Li L. S.,Lu S. Z.,&Huang S. H..(1999).Crystal structure and luminescence of europium 4-methoxybenzoate complex with 2,2 '-bipyridine Eu(p-MOBA)(3)bipy center dot 1/2C(2)H(5)OH.Polyhedron,18(3—4),487-491. |
MLA | Jin L. P.,et al."Crystal structure and luminescence of europium 4-methoxybenzoate complex with 2,2 '-bipyridine Eu(p-MOBA)(3)bipy center dot 1/2C(2)H(5)OH".Polyhedron 18.3—4(1999):487-491. |
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