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Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity)
其他题名论文其他题名
Li X.; Zheng X.; Jin L.; Lu S.; Qin W.
2000
发表期刊Journal of Molecular Structure
ISSN0022-2860
卷号519页码:85-91
摘要The structure of the complex [Eu(m-MOBA)(3). 2H(2)O]1/2(4,4'-bpy) (m-MOBA: m-methoxybenzoate, 4,4'-bpy: 4,4'-bipyridine) was determined by single crystal X-ray diffraction. The bonding around each europium consists of two oxygen atoms of the chelated carboxyl group, two oxygen atoms of two water molecules and four oxygen atoms of the bidentate bridging carboxylate groups, forming an infinite polymeric chain structure. The luminescence behaviour of Eu3+ in {[Eu(m-MOBA)(3). 2H(2)O]1/2(4,4'-bpy)}(infinity) was observed at 77 K. The emission spectra of D-5(1) --> F-7(J) (J = 1-3) and D-5(0) --> F-7(J) (J = 0-4) transitions were recorded. The complex displays intense luminescence which may be related to the m-MOBA ligand and the polymeric coordination. (C) 2000 Elsevier Science B.V. All rights reserved.
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/25258
专题中科院长春光机所知识产出
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Li X.,Zheng X.,Jin L.,et al. Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity)[J]. Journal of Molecular Structure,2000,519:85-91.
APA Li X.,Zheng X.,Jin L.,Lu S.,&Qin W..(2000).Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity).Journal of Molecular Structure,519,85-91.
MLA Li X.,et al."Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity)".Journal of Molecular Structure 519(2000):85-91.
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