Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity) | |
其他题名 | 论文其他题名 |
Li X.; Zheng X.![]() | |
2000 | |
发表期刊 | Journal of Molecular Structure
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ISSN | 0022-2860 |
卷号 | 519页码:85-91 |
摘要 | The structure of the complex [Eu(m-MOBA)(3). 2H(2)O]1/2(4,4'-bpy) (m-MOBA: m-methoxybenzoate, 4,4'-bpy: 4,4'-bipyridine) was determined by single crystal X-ray diffraction. The bonding around each europium consists of two oxygen atoms of the chelated carboxyl group, two oxygen atoms of two water molecules and four oxygen atoms of the bidentate bridging carboxylate groups, forming an infinite polymeric chain structure. The luminescence behaviour of Eu3+ in {[Eu(m-MOBA)(3). 2H(2)O]1/2(4,4'-bpy)}(infinity) was observed at 77 K. The emission spectra of D-5(1) --> F-7(J) (J = 1-3) and D-5(0) --> F-7(J) (J = 0-4) transitions were recorded. The complex displays intense luminescence which may be related to the m-MOBA ligand and the polymeric coordination. (C) 2000 Elsevier Science B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25258 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Li X.,Zheng X.,Jin L.,et al. Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity)[J]. Journal of Molecular Structure,2000,519:85-91. |
APA | Li X.,Zheng X.,Jin L.,Lu S.,&Qin W..(2000).Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity).Journal of Molecular Structure,519,85-91. |
MLA | Li X.,et al."Crystal structure and luminescence of a europium coordination polymer { Eu(m-MOBA)(3)center dot 2H(2)O 1/2(4,4 '-bpy)}(infinity)".Journal of Molecular Structure 519(2000):85-91. |
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