Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Crystal structure and luminescence of a europium 3-methoxybenzoate complex with 2,2 '-bipyridine | |
其他题名 | 论文其他题名 |
Li X.; Bian Z. Q.; Jin L. P.; Lu S. Z.; Huang S. H. | |
2000 | |
发表期刊 | Journal of Molecular Structure |
ISSN | 0022-2860 |
卷号 | 522页码:117-123 |
摘要 | The structure of the dimer [Eu(m-MOBA)(3). 2,2'-bipy](2) (m-MOBA: m-methoxybenzoate, 2,2'-bipy: 2,2'-bipyridine) was determined by single crystal X-ray diffraction. Each europium atom is coordinated with two oxygen atoms of the chelated carboxyl group, four oxygen atoms of the bidentate bridging carboxylate groups and two nitrogen atoms from a 2,2'-bipyridine molecule forming a dimeric structure with coordination number 8. The luminescence behaviour of the Eu3+ ion in [Eu(m-MOBA)(3). 2,2'-bipy](2) was observed at 77 K, The emission spectra of D-5(1) --> F-7(J) (J = 1-3) and D-5(0) --> F-7(J) (J = 0-4) transitions were measured, The complex displays intense luminescence and the Eu3+ ions in the dimer occur in slightly different chemical environments. (C) 2000 Elsevier Science B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25257 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Li X.,Bian Z. Q.,Jin L. P.,et al. Crystal structure and luminescence of a europium 3-methoxybenzoate complex with 2,2 '-bipyridine[J]. Journal of Molecular Structure,2000,522:117-123. |
APA | Li X.,Bian Z. Q.,Jin L. P.,Lu S. Z.,&Huang S. H..(2000).Crystal structure and luminescence of a europium 3-methoxybenzoate complex with 2,2 '-bipyridine.Journal of Molecular Structure,522,117-123. |
MLA | Li X.,et al."Crystal structure and luminescence of a europium 3-methoxybenzoate complex with 2,2 '-bipyridine".Journal of Molecular Structure 522(2000):117-123. |
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