Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Fluorescence properties of divalent and trivalent europium ions in aluminosilicate glasses | |
其他题名 | 论文其他题名 |
Song H. W.; Lu S. Z.; E S. L.; Gao R. X.; Zhang J. H.; Chen B. J.; Xia H. P.; Zhang J. L.; Ni Q. H. | |
2002 | |
发表期刊 | Journal of Applied Physics |
ISSN | 0021-8979 |
卷号 | 91期号:5页码:2959-2964 |
摘要 | Optical absorption, fluorescence, excitation and time-resolved spectra, and fluorescence dynamics were studied in Eu2+- and Eu3+-codoped aluminosilicate glasses. The results indicated that the energy transfer occurred between Eu2+ and Eu3+ ions, in which the energy corresponding to the 4f(6)5d to S-8(7/2) transition of Eu2+ ions caused excitation of the Eu3+ ions to the D-5(J) level. Some of the electrons in the ground state F-7(0) were thermally excited into the F-7(1) state at room temperature, and thermal populations of the F-7(1) level had great effects on the spectral shape of the D-5(0)-F-7(2) emission. The effect of light irradiation at different wavelengths on fluorescence was systemically studied. The visible, ultraviolet and x-ray irradiation caused a decrease in the fluorescence of Eu2+ and/or Eu3+ ions. Frequency selective excitation experiments were performed at 10 K and room temperature. Instead of forming a spectral hole, the intensity of the F-7(0)-D-5(0) transition decreased as a whole. This was attributed to the interaction of Eu3+ ions with the two-level systems existing in the glass network. (C) 2002 American Institute of Physics. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/25200 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Song H. W.,Lu S. Z.,E S. L.,et al. Fluorescence properties of divalent and trivalent europium ions in aluminosilicate glasses[J]. Journal of Applied Physics,2002,91(5):2959-2964. |
APA | Song H. W..,Lu S. Z..,E S. L..,Gao R. X..,Zhang J. H..,...&Ni Q. H..(2002).Fluorescence properties of divalent and trivalent europium ions in aluminosilicate glasses.Journal of Applied Physics,91(5),2959-2964. |
MLA | Song H. W.,et al."Fluorescence properties of divalent and trivalent europium ions in aluminosilicate glasses".Journal of Applied Physics 91.5(2002):2959-2964. |
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