Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid

	Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid
其他题名	论文其他题名
	Wan Y. H.; Jin L. P.; Wang K. Z.; Zhang L. P.; Zheng X. J.; Lu S. Z.
	2002
发表期刊	New Journal of Chemistry
ISSN	1144-0546
卷号	26 期号:11 页码:1590-1596
摘要	This paper presents four lanthanide coordination polymers, [Ln(2)(BDC)(3)(H2O)](n) (Ln = La, 1; Ln = Eu, 2; Ln = Tb, 3; BDC = 1,2-benzenedicarboxylate) and [Yb-4(BDC)(6)(H2O)(2)](n) (4) prepared by the hydrothermal technique. They are all 2-D infinite structures with BDC anions connecting adjacent metal ions. In complex 1, La(m) ions are eight- and nine-coordinated, and all La(m) ions are coplanar in the 2-D structure. In complexes 2 and 3, Eu(III) and Tb(III) ions are also eight- and nine-coordinated, but they are distributed in a wave-like 2-D network. In complex 4, the Yb(III) ions have four different coordination numbers (6, 7, 8 and 9), which are rarely found in one lanthanide complex. Both the coordination numbers and the arrangement of Ln atoms in these coordination polymers show the lanthanide contraction. In the four complexes, all the oxygen atoms of BDC take part in coordination with Ln(III) ions, adopting tetra-, penta- and hexadentate coordination modes for the phthalate anions. The luminescent properties of complex 2 have been investigated and the results for the explanation of the chemical environment of the Eu(III) ion are consistent with the X-ray analysis.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/25188
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Wan Y. H.,Jin L. P.,Wang K. Z.,et al. Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid[J]. New Journal of Chemistry,2002,26(11):1590-1596.
APA	Wan Y. H.,Jin L. P.,Wang K. Z.,Zhang L. P.,Zheng X. J.,&Lu S. Z..(2002).Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid.New Journal of Chemistry,26(11),1590-1596.
MLA	Wan Y. H.,et al."Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid".New Journal of Chemistry 26.11(2002):1590-1596.

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