Synthesis, structure and luminescence property of the three ternary and quaternary europium complexes

	Synthesis, structure and luminescence property of the three ternary and quaternary europium complexes
其他题名	论文其他题名
	Li X.; Jin L. P.; Zheng X. J.; Lu S. Z.; Zhang J. H.
	2002
发表期刊	Journal of Molecular Structure
ISSN	0022-2860
卷号	607 期号:1 页码:59-67
摘要	Three binuclear europium complexes containing bidentate and tridentate bridging carboxylates with diimines, namely [Eu(m-MOBA)(2)NO(3)phen](2), [Eu(2,3-DMOBA)(2)NO(3)Phen](2) and [Eu(2,3-DMOBA)(3)bpy](2) (in-MOBA = 3-methoxybenzoate, 2,3-DMOBA = 2,3-dimethoxy-benzoate, phen = 1,10-phenanthroline, bpy = 2,2'-bipyridine), have been synthesized and characterized by X-ray diffraction. The two europium(III) ions in each dimer are bridged by the four carboxylato groups in which two of them are the bidentate bridging mode, and the other two the tridentate bridging mode. The crystallographic data and combination bands of infrared spectra of the [Eu(m-MOBA)(2)NO(3)phen](2) and the [Eu(2,3-DMOBA)(2)NO(3)phen](2) complexes show that the nitrato group is bidentate, and thus each europium(III) ion in the complexes is coordinated with seven oxygen atoms and two nitrogen atoms from phen, leading to a dimeric structure with coordination number 9. Excitation and emission spectra of the europium complexes were observed at 77 K. The D-5(u) --> F-7(J) (J = 0-4) luminescence spectra show that the europium(III) ion site in the crystals of the three europium complexes has C, symmetry. The slightly different chemical environments of the europium(III) ions in the [Eu(2,3-DMOBA)(3)bpy](2) complex is confirmed by its emission spectra. (C) 2002 Elsevier Science B.V. All rights reserved.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/25187
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Li X.,Jin L. P.,Zheng X. J.,et al. Synthesis, structure and luminescence property of the three ternary and quaternary europium complexes[J]. Journal of Molecular Structure,2002,607(1):59-67.
APA	Li X.,Jin L. P.,Zheng X. J.,Lu S. Z.,&Zhang J. H..(2002).Synthesis, structure and luminescence property of the three ternary and quaternary europium complexes.Journal of Molecular Structure,607(1),59-67.
MLA	Li X.,et al."Synthesis, structure and luminescence property of the three ternary and quaternary europium complexes".Journal of Molecular Structure 607.1(2002):59-67.

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