Syntheses, structures, and properties of lanthanide supramolecular complexes with 1,10-phenanthroline and terminal amino acids with different chain lengths

	Syntheses, structures, and properties of lanthanide supramolecular complexes with 1,10-phenanthroline and terminal amino acids with different chain lengths
其他题名	论文其他题名
	Zheng X. J.; Jin L. P.; Lu S. Z.; Zheng Y. Q.
	2003
发表期刊	Zeitschrift Fur Anorganische Und Allgemeine Chemie
ISSN	0044-2313
卷号	629 期号:14 页码:2577-2584
摘要	Four lanthanide supramolecular coordination compounds, [Eu(gly)(2)(phen)(2)(H2O)(2)](ClO4)(3)(phen)(4)(H2O)-H-. (1), [Eu-2(APA)(6)(phen)(2)](ClO4)(6)(phen)(4) (.)3H(2)O (2), [Tb-2(ABA)(4)(phen)(4)](ClO4)(6)(phen)(4) (3), and [Eu-2(AHA)(4)(phen)(4)](ClO4)(6)(phen)(2)(.)2H(2)O(.)2C(2)H(5)OH (4) (gly = glycine, APA = 3-aminopropionic acid, ABA = 4-aminobutanoic acid, AHA = 6-aminohexanoic acid, phen = 1,10-phenanthroline), were synthesized and characterized by single crystal X-ray diffraction. Compound 1 has a 2-D supramolecular layered structure of mononuclear coordination cations and free phen molecules connected via hydrogen bonding and pi-pi stacking interactions. 2 forms a 3-D supramolecular network by hydrogen bonding between binuclear coordination cations and free phen molecules, between coordination cations and lattice water molecules, and pi-pi stacking interactions between free phen molecules. Compounds 3 and 4 form 2-D supramolecular structures with pi-pi stacking between coordinating phen molecules, and between free phen molecules hydrogen-bonded to the binuclear coordination cations. The high-resolution emission spectra show only one Eu3+ ion site in the title complexes. The aqueous solutions of the title complexes are all photochromic with the color of the solution changing from yellow to green when irradiated by mercury lamp. During the decoloration process, they return to yellow color.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/25157
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Zheng X. J.,Jin L. P.,Lu S. Z.,et al. Syntheses, structures, and properties of lanthanide supramolecular complexes with 1,10-phenanthroline and terminal amino acids with different chain lengths[J]. Zeitschrift Fur Anorganische Und Allgemeine Chemie,2003,629(14):2577-2584.
APA	Zheng X. J.,Jin L. P.,Lu S. Z.,&Zheng Y. Q..(2003).Syntheses, structures, and properties of lanthanide supramolecular complexes with 1,10-phenanthroline and terminal amino acids with different chain lengths.Zeitschrift Fur Anorganische Und Allgemeine Chemie,629(14),2577-2584.
MLA	Zheng X. J.,et al."Syntheses, structures, and properties of lanthanide supramolecular complexes with 1,10-phenanthroline and terminal amino acids with different chain lengths".Zeitschrift Fur Anorganische Und Allgemeine Chemie 629.14(2003):2577-2584.

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