Changchun Institute of Optics,Fine Mechanics and Physics,CAS
New lanthanide coordination polymers of 1,2,4,5-benzenetetracarboxylic acid and 4,4-bipyridine with 1D channels | |
其他题名 | 论文其他题名 |
Wang Y. B.; Zhuang W. J.; Jin L. P.; Lu S. Z. | |
2005 | |
发表期刊 | Journal of Molecular Structure
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ISSN | 0022-2860 |
卷号 | 737期号:2—3页码:165-172 |
摘要 | Three new lanthanide coordination polymers with 1,2,4,5-benzenetetracarboxylic acid, Pr-2(betc)(2)(4,4'-bpyH(2)).0.25H(2)O (1), Ln(2)(betc)(2)(4,4'-bpyH(2)) (Ln = Eu (2), Gd (3)) were hydrothermally prepared. The crystallographic data of 1-3 show that they are isostructural, and possess 3D framework with 1D rhomboid channels, where the 4,4-bipyridine molecules exist steadily via hydrogen bonds. Meanwhile, a supramolecular structure of (4,4-bpyH(2))(2)(betc) (4) was also obtained by hydrothermal reaction. The results of 1-4 indicate that 4,4'-bipyridine molecule acting as a template plays an important role in the formation of complexes 1-3, and thus has a synergistic action in the construction of 3D framework with large channels. (C) 2004 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/24988 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Wang Y. B.,Zhuang W. J.,Jin L. P.,et al. New lanthanide coordination polymers of 1,2,4,5-benzenetetracarboxylic acid and 4,4-bipyridine with 1D channels[J]. Journal of Molecular Structure,2005,737(2—3):165-172. |
APA | Wang Y. B.,Zhuang W. J.,Jin L. P.,&Lu S. Z..(2005).New lanthanide coordination polymers of 1,2,4,5-benzenetetracarboxylic acid and 4,4-bipyridine with 1D channels.Journal of Molecular Structure,737(2—3),165-172. |
MLA | Wang Y. B.,et al."New lanthanide coordination polymers of 1,2,4,5-benzenetetracarboxylic acid and 4,4-bipyridine with 1D channels".Journal of Molecular Structure 737.2—3(2005):165-172. |
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