Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4 '-oxybis(benzoic acid)

	Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4 '-oxybis(benzoic acid)
其他题名	论文其他题名
	Wang Y. B.; Sun C. Y.; Zheng X. J.; Gao S.; Lu S. Z.; Jin L. P.
	2005
发表期刊	Polyhedron
ISSN	0277-5387
卷号	24 期号:7 页码:823-830
摘要	Three new polynuclear lanthanide coordination polymers [Ln(5)(μ(3)-OH)(oba)(7)(H2O)(2)](n)(.)0.5nH(2)O (Ln = Eu (1), Ho (2)) and [Yb-6(oba)(9)(H2O)](n) (3) (H(2)oba = 4,4'-oxybis(benzoic acid)), were prepared by hydrothermal reactions. 1 and 2 are isomorphous and exhibit complicated three-dimensional structures based on [Ln(5)(μ(3)-OH)(oba)(7)(H2O)(2)] building blocks. In the asymmetric unit, there are five different coordination environments of Ln(III) ions, including a trinuclear hydroxo core. Complex 3 is a three-dimensional coordination polymer built tip from a hexanuclear building block. In 3, Yb(III) ions have six different chemical environments and are in a regular arrangement, resulting in pseudohexagonal prisms along the α-axis. The luminescent property of 1 and magnetic behaviors of 2 and 3 have also been studied. © 2005 Elsevier Ltd. All rights reserved.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/24987
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Wang Y. B.,Sun C. Y.,Zheng X. J.,et al. Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4 '-oxybis(benzoic acid)[J]. Polyhedron,2005,24(7):823-830.
APA	Wang Y. B.,Sun C. Y.,Zheng X. J.,Gao S.,Lu S. Z.,&Jin L. P..(2005).Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4 '-oxybis(benzoic acid).Polyhedron,24(7),823-830.
MLA	Wang Y. B.,et al."Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4 '-oxybis(benzoic acid)".Polyhedron 24.7(2005):823-830.

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