Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Photovoltaic effects of diodes containing lanthanide complexes | |
其他题名 | 论文其他题名 |
Chu B.; Li W. L.; Wei H. Z.; Wang D. Y.; Li M. T.; Zhang Z. Q.; Hu Z. Z.; Lee C. S.; Lee S. T. | |
2005 | |
发表期刊 | Journal of Alloys and Compounds |
ISSN | 0925-8388 |
卷号 | 389期号:1—2页码:252-255 |
摘要 | We present a systematic study of organic photovoltaic (PV) diodes containing a series of lanthanide (Ln) complexes, tris(dibenzoylmethanato) (monobathophenanthroline) (Ln)(III) [Ln(DBM)(3) bath] used as an electron acceptor. For making a convenient comparison among all diodes, they were fabricated by adopting the same structure, ITO/N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-diphenyl-4,4-diamine (TPD) (30 nm)/Ln(DBM)(3) bath (60 nm)/Mg:Ag (200 nm), which was not optimized. Although these diodes under bias voltage almost show an exciplex emission relating to PV effects, they indicate distinct performances due to their different 4f electrons and f(n) configurations. Especially, the PV effects of the diodes containing La3+ (4f(0)), Y3+ (4f(7)), Gd3+ (4f(7)), and Lu3+ (4f(14))-complexes having the relative stable electron configurations in the 4f orbital are best under illumination with 365 nm UV light. And the diodes containing Pr3+, Yb3+-, and Sm(3+-)complexes have better PV effects, the other diodes containing Ln(DBM)3 bath (Ln: Nd, Eu, Tb, Dy, Ho, Er and Tm) only show poor PV effects. (C) 2004 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/24979 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Chu B.,Li W. L.,Wei H. Z.,et al. Photovoltaic effects of diodes containing lanthanide complexes[J]. Journal of Alloys and Compounds,2005,389(1—2):252-255. |
APA | Chu B..,Li W. L..,Wei H. Z..,Wang D. Y..,Li M. T..,...&Lee S. T..(2005).Photovoltaic effects of diodes containing lanthanide complexes.Journal of Alloys and Compounds,389(1—2),252-255. |
MLA | Chu B.,et al."Photovoltaic effects of diodes containing lanthanide complexes".Journal of Alloys and Compounds 389.1—2(2005):252-255. |
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