Synthesis, crystal structure and electroluminescent properties of a Schiff base zinc complex

	Synthesis, crystal structure and electroluminescent properties of a Schiff base zinc complex
其他题名	论文其他题名
	Yu T. Z.; Su W. M.; Li W. L.; Hong Z. R.; Hua R. N.; Li M. T.; Chu B.; Li B.; Zhang Z. Q.; Hu Z. Z.
	2006
发表期刊	Inorganica Chimica Acta
ISSN	0020-1693
卷号	359 期号:7 页码:2246-2251
摘要	A new complex of zinc with a Schiff base, zinc(NN'-bis(salicylidene)-3, 6-dioxa-1, 8-diaminooctane monohydrate) (ZnBSO center dot H2O), was synthesized and characterized by means of elemental analyses, IR spectra and DTA-TG. Its structure was determined by X-ray single crystal analysis. It was demonstrated that the zinc atom is coordinated by the two oxygen atoms in phenolate and two nitrogen atoms in imine of the ligand in a slightly distorted tetrahedral geometry, while the two oxygen atoms from the oxa-alkyl chain are not coordinated to Zn(II) atom. The energy levels of the HOMO, LUMO and the electrochemical band gap were determined by cyclic voltammeter. The electroluminescent devices with the complex as the emitter showed bright blue emission with a peak at 450 nm, which is same as the fluorescence of the complex in both solution and solid states. (c) 2006 Elsevier B.V. All rights reserved.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/24968
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Yu T. Z.,Su W. M.,Li W. L.,et al. Synthesis, crystal structure and electroluminescent properties of a Schiff base zinc complex[J]. Inorganica Chimica Acta,2006,359(7):2246-2251.
APA	Yu T. Z..,Su W. M..,Li W. L..,Hong Z. R..,Hua R. N..,...&Hu Z. Z..(2006).Synthesis, crystal structure and electroluminescent properties of a Schiff base zinc complex.Inorganica Chimica Acta,359(7),2246-2251.
MLA	Yu T. Z.,et al."Synthesis, crystal structure and electroluminescent properties of a Schiff base zinc complex".Inorganica Chimica Acta 359.7(2006):2246-2251.

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