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The contribution of the coordinated water to D-5(4) population in YPO4 hydrates doped with low concentration of Tb3+
其他题名论文其他题名
Di W. H.; Wang X. J.; Pan G. H.; Bai X.; Chen B. J.; Ren X. G.
2007
发表期刊Chemical Physics Letters
ISSN0009-2614
卷号436期号:1—3页码:129-132
摘要This work reports an interesting result on the photoluminescence OfYP04. 21420 doped with low concentration of Tb which was synthesized at low temperature by aqueous route. In the as-synthesized Y0.098PO4:Tb-0.002 . 2H(2)O, in which the hydration water is coordinated to the rare earth ions, the emissions of D-5(4) of Tb3+ are much more intense than the emissions of D-5(3). After dehydration by annealing, an opposite result is achieved, i.e., the emissions of D-5(4) of Tb3+ are much lower than the emissions of D-5(3). The Fourier-transform infrared (FTIR) and fluorescent decay spectra demonstrate that the coordinated water molecule in the hydrated sample contributes to the relaxation of D-5(3) to D-5(4), thus increasing the population of the excited state D-5(4) of Tb3+ in the as-synthesized sample. (c) 2007 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/24878
专题中科院长春光机所知识产出
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Di W. H.,Wang X. J.,Pan G. H.,et al. The contribution of the coordinated water to D-5(4) population in YPO4 hydrates doped with low concentration of Tb3+[J]. Chemical Physics Letters,2007,436(1—3):129-132.
APA Di W. H.,Wang X. J.,Pan G. H.,Bai X.,Chen B. J.,&Ren X. G..(2007).The contribution of the coordinated water to D-5(4) population in YPO4 hydrates doped with low concentration of Tb3+.Chemical Physics Letters,436(1—3),129-132.
MLA Di W. H.,et al."The contribution of the coordinated water to D-5(4) population in YPO4 hydrates doped with low concentration of Tb3+".Chemical Physics Letters 436.1—3(2007):129-132.
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