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Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning
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Dong B.; Song H. W.; Yu H. Q.; Zhang H.; Qin R. F.; Bai X.; Pan G. H.; Lu S. Z.; Wang F.; Fan L. B.; Dai Q. L.
2008
发表期刊Journal of Physical Chemistry C
ISSN1932-7447
卷号112期号:5页码:1435-1440
摘要Ln(3+) doped (Yb3+,Tm3+ codoped and Yb3+,Er3+,Tm3+ tridoped) NaYF4/poly(vinyl pyrrolidone)(PVP) (M-w approximate to 5 1300 000) composite fibers with an average diameter of 300-800 nm were prepared by electrospinning and characterized by X-ray diffraction, field emission scanning electron micrography, and Fourier transform infrared spectra. Their upconversion (UC) luminescence properties were studied in contrast to the corresponding Ln(3+) doped NaYF4 nanoparticles (15-20 nm) under 980-nm excitation. The results demonstrate that in the Yb3+,TM3+ codoped composite fibers the blue emission of (1)G(4)-H-1(6) is dominantly strong, while in the nanoparticles the red emission of F-3(2,3)-H-3(6) Contributes considerably to the increase of the excitation power. This indicates that the color purity of blue is improved greatly by the modification of PVP. In the tridoped Yb3+,Er3+, TM3+ composite fibers, white light with more stable color balance (blue (1)G(4)-H-3(6) of Tm3+, green H-2(11/2)/S-4(3/2)-I-4(15/2), and red F-4(9/2)-I-4(15/2) of Er3+) was obtained. The improved UC properties in the composite fibers are attributed to the suppressed local thermal effect. The energy transfer and UC populating processes are discussed.
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/24851
专题中科院长春光机所知识产出
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Dong B.,Song H. W.,Yu H. Q.,et al. Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning[J]. Journal of Physical Chemistry C,2008,112(5):1435-1440.
APA Dong B..,Song H. W..,Yu H. Q..,Zhang H..,Qin R. F..,...&Dai Q. L..(2008).Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning.Journal of Physical Chemistry C,112(5),1435-1440.
MLA Dong B.,et al."Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning".Journal of Physical Chemistry C 112.5(2008):1435-1440.
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