Changchun Institute of Optics,Fine Mechanics and Physics,CAS
Energy transfer in Y3Al5O12:Ce3+, Pr3+ and CaMoO4:Sm3+, Eu3+ phosphors | |
其他题名 | 论文其他题名 |
Zhang J. H.; Wang L.; Jin Y.; Zhang X.; Hao Z. D.; Wang X. J. | |
2011 | |
发表期刊 | Journal of Luminescence |
ISSN | 0022-2313 |
卷号 | 131期号:3页码:429-432 |
摘要 | Non-radiative energy transfers (ET) from Ce3+ to Pr3+ in Y3Al5O12:Ce3+, Pr3+ and from Sm3+ to Eu3+ in CaMoO4:Sm3+, Eu3+ are studied based on photoluminescence spectroscopy and fluorescence decay patterns. The result indicates an electric dipole-dipole interaction that governs ET in the LED phosphors. For Ce3+ concentration of 0.01 in YAG:Ce3+, Pr3+, the rate constant and critical distance are evaluated to be 4.5 x 10(-36) cm(6) s(-1) and 0.81 nm, respectively. An increase in the red emission line of Pr3+ relative to the yellow emission band of Ce3+, on increasing Ce3+ concentration is observed. This behavior is attributed to the increase of spectral overlap integrals between Ce3+ emission and Pr3+ excitation due to the fact that the yellow band shifts to the red spectral side with increasing Ce3+. concentration. In CaMoO4:Sm3+, Eu3+, Sm3+-Eu3+ transfer occurs from (4)G(5/2) of Sm3+ to D-5(0) of Eu3+. The rate constant of 8.5 x 10(-40) cm(6) s(-1) and the critical transfer distance of 0.89 nm are evaluated. (C) 2010 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/24725 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Zhang J. H.,Wang L.,Jin Y.,et al. Energy transfer in Y3Al5O12:Ce3+, Pr3+ and CaMoO4:Sm3+, Eu3+ phosphors[J]. Journal of Luminescence,2011,131(3):429-432. |
APA | Zhang J. H.,Wang L.,Jin Y.,Zhang X.,Hao Z. D.,&Wang X. J..(2011).Energy transfer in Y3Al5O12:Ce3+, Pr3+ and CaMoO4:Sm3+, Eu3+ phosphors.Journal of Luminescence,131(3),429-432. |
MLA | Zhang J. H.,et al."Energy transfer in Y3Al5O12:Ce3+, Pr3+ and CaMoO4:Sm3+, Eu3+ phosphors".Journal of Luminescence 131.3(2011):429-432. |
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