Crystal structure and luminescence properties of Lu3+ and Mg2+ incorporated silicate garnet Ca3-(x+0.06)LuxCe0.06 (Sc2-yMgy)Si3O12

	Crystal structure and luminescence properties of Lu3+ and Mg2+ incorporated silicate garnet Ca3-(x+0.06)LuxCe0.06 (Sc2-yMgy)Si3O12
其他题名	论文其他题名
	Liu Y. F.; Zhang X.; Hao Z. D.; Luo Y. S.; Wang X. J.; Zhang J. H.
	2012
发表期刊	Journal of Luminescence
ISSN	0022-2313
卷号	132 期号:5 页码:1257-1260
摘要	; The yellow-emitting phosphor [Ca3-(x+0.06)LuxCe0.06](Sc2-yMgy)Si3O12 obtained from Lu3+ and Mg2+ co-modified green-emitting silicate garnet Ca3Sc2Si3O12:Ce3+ (CSS:Ce3+) exhibits promising applications for white LEDs. In this paper, we discuss the effect of charge balance on the garnet structure formation. The changes of bond length and covalence caused by the replacement of Lu3+ and Mg2+ for Ca2+ and Sc3+ are analyzed. The shift of the Ce3+ emission and excitation can be attributed to the combined results from crystal field splitting effect and centroid shift of Ce3+ 5d levels. Thermal stability is analyzed according to configurational coordinate diagram. (C) 2011 Elsevier B.V. All rights reserved.
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/24703
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Liu Y. F.,Zhang X.,Hao Z. D.,et al. Crystal structure and luminescence properties of Lu3+ and Mg2+ incorporated silicate garnet Ca3-(x+0.06)LuxCe0.06 (Sc2-yMgy)Si3O12[J]. Journal of Luminescence,2012,132(5):1257-1260.
APA	Liu Y. F.,Zhang X.,Hao Z. D.,Luo Y. S.,Wang X. J.,&Zhang J. H..(2012).Crystal structure and luminescence properties of Lu3+ and Mg2+ incorporated silicate garnet Ca3-(x+0.06)LuxCe0.06 (Sc2-yMgy)Si3O12.Journal of Luminescence,132(5),1257-1260.
MLA	Liu Y. F.,et al."Crystal structure and luminescence properties of Lu3+ and Mg2+ incorporated silicate garnet Ca3-(x+0.06)LuxCe0.06 (Sc2-yMgy)Si3O12".Journal of Luminescence 132.5(2012):1257-1260.

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