Changchun Institute of Optics,Fine Mechanics and Physics,CAS
A new dual-emission phosphor Ca4Si2O7F2:Ce3+, Mn2+ with energy transfer for near-UV LEDs | |
其他题名 | 论文其他题名 |
Lu W.; Luo Y. S.; Hao Z. D.; Zhang X.; Wang X. J.; Zhang J. H. | |
2012 | |
发表期刊 | Materials Letters |
ISSN | 0167-577X |
卷号 | 77页码:45-47 |
摘要 | Ce3+ and Mn2+ co-doped Ca4Si2O7F2 phosphors have been synthesized by high temperature solid state reaction and their luminescence properties are investigated. The effect of Ce3+ concentration on the emission intensity of Ca4Si2O7F2: Ce3+ is studied, and the emission intensity reaches a maximum at 4% Ce3+. Energy transfer from Ce3+ to Mn2+ is observed. The emission spectra of the phosphors show a blue broad band at 460 nm of Ce3+ and a yellow band at 580 nm of Mn2+, originate from the allowed 5d -> 4f transition of the Ce3+ ion and the T-4(1g)((4)G) -> (6)A(1g)(S-6) transition of the Mn2+ ion, respectively. Results indicate that the varied emitted color from blue to yellow can be achieved by tuning the relative ratio of the Ce3+ to Mn2+ ions based on the principle of energy transfer. We have demonstrated that Ca4Si2O7F2: Ce3+, Mn2+ phosphors can be a promising candidate for a color-tunable phosphor applied in a near-UV White light emitting diodes. (C) 2012 Elsevier B.V. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ciomp.ac.cn/handle/181722/24672 |
专题 | 中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Lu W.,Luo Y. S.,Hao Z. D.,et al. A new dual-emission phosphor Ca4Si2O7F2:Ce3+, Mn2+ with energy transfer for near-UV LEDs[J]. Materials Letters,2012,77:45-47. |
APA | Lu W.,Luo Y. S.,Hao Z. D.,Zhang X.,Wang X. J.,&Zhang J. H..(2012).A new dual-emission phosphor Ca4Si2O7F2:Ce3+, Mn2+ with energy transfer for near-UV LEDs.Materials Letters,77,45-47. |
MLA | Lu W.,et al."A new dual-emission phosphor Ca4Si2O7F2:Ce3+, Mn2+ with energy transfer for near-UV LEDs".Materials Letters 77(2012):45-47. |
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