Na3TbSi3O9&middot3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels

	Na3TbSi3O9&middot3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels
其他题名	论文其他题名
	Wang G.; Li J.; Yu J.; Chen P.; Pan Q.; Song H.; Xu R.
	2006
发表期刊	Chemistry of Materials
ISSN	8974756
卷号	18 期号:24 页码:5637-5639
摘要	The structure and preparation of a new luminescent microporous terbium silicate Na3TbSi3O9.3H2O (TbSiO-CJ1) crystallized in the enantiomorphic space group P212 121 were analyzed. The structure was featured by a A-Co(en)3 such as chiral unit of [TbSi6O9] and contained helical sechser silicate chains and 9- ring channels. TbSiO-CJI was prepared by the mild hydrothermal reaction of a mixture of fumed silica and water in a 1.0:0.12:8.46:58 molar ratio at 230C for 6 days in a Teflon lined stainless steel autoclave. The single crystal unit revealed that TbSiO-CJI is composed of a macroanionic [TbSi3O9]3- framework. The Na positive ions residing in the channels compensated the negative charge of the inorganic framework. Results show that a new terbium silicate has been synthesized under mild hydrothermal conditions.
收录类别	EI
文献类型	期刊论文
条目标识符	http://ir.ciomp.ac.cn/handle/181722/24545
专题	中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Wang G.,Li J.,Yu J.,et al. Na3TbSi3O9&middot3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels[J]. Chemistry of Materials,2006,18(24):5637-5639.
APA	Wang G..,Li J..,Yu J..,Chen P..,Pan Q..,...&Xu R..(2006).Na3TbSi3O9·3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels.Chemistry of Materials,18(24),5637-5639.
MLA	Wang G.,et al."Na3TbSi3O9·3H2O: A new luminescent microporous terbium(III) silicate containing helical sechser silicate chains and 9-ring channels".Chemistry of Materials 18.24(2006):5637-5639.

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