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Dynamical processes of energy transfer in red emitting phosphor CaMoO 4:Sm3+, Eu3+
其他题名论文其他题名
Jin Y.; Hao Z.; Zhang X.; Luo Y.; Wang X.; Zhang J.
2011
发表期刊Optical Materials
ISSN9253467
卷号33期号:11页码:1591-1594
摘要Upon 4K11/2 excitation of Sm3+ at 405 nm, the performance of energy transfer from Sm3+ to Eu3+ in the red emitting phosphor CaMoO4:Eu3+, Sm3+ significantly extends its excitation region for better matching the near-UV LED. Photoluminescence spectra indicate that the energy transfer pathway concerns the relaxation from 4K11/2 to 4G5/2 of Sm3+ and subsequent transfer to 5D0 of Eu3+ rather than 5D1 of Eu3+. The fluorescent decay pattern of Sm3+ 4G5/2 level in CaMoO4:0.5% Sm3+, 2% Eu3+ is studied at 77 K based on the Inokuti-Hirayama formula, revealing an electronic dipole-dipole interaction between Sm3+ and Eu3+. The coefficient for the energy transfer is obtained to be 8.5 10-40 s-1 cm6. The fluorescence rise and decay pattern of Eu3+ 5D0 level as Sm3+ is only excited at 77 K is well described by the dynamical processes of the energy transfer. 2011 Elsevier B.V. All rights reserved.
收录类别EI
文献类型期刊论文
条目标识符http://ir.ciomp.ac.cn/handle/181722/24437
专题中科院长春光机所知识产出
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Jin Y.,Hao Z.,Zhang X.,et al. Dynamical processes of energy transfer in red emitting phosphor CaMoO 4:Sm3+, Eu3+[J]. Optical Materials,2011,33(11):1591-1594.
APA Jin Y.,Hao Z.,Zhang X.,Luo Y.,Wang X.,&Zhang J..(2011).Dynamical processes of energy transfer in red emitting phosphor CaMoO 4:Sm3+, Eu3+.Optical Materials,33(11),1591-1594.
MLA Jin Y.,et al."Dynamical processes of energy transfer in red emitting phosphor CaMoO 4:Sm3+, Eu3+".Optical Materials 33.11(2011):1591-1594.
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